Anyone transporting dangerous goods on the road must take an examination. The German Chamber of Commerce and Industry (IHK) administers this examination and then issues the so-called ADR certificate. Here you can find the model statute (PDF, 248 KB).
We provide the training schedules for dangerous goods drivers here for download (available in German only):
Legal Regulations for the Transport of Dangerous Goods
The Federal Ministry of Transport offers a summary of applicable dangerous goods regulations on its website:
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